大采高工作面过断层破碎带围岩控制技术研究

为了研究大采高工作面断层破碎带围岩控制技术,采用UDEC分别模拟工作面揭露断层前后围岩应力变化规律、揭露断层时覆岩运移规律。根据模拟结果可知,断层导致工作面应力呈"几"字型分布及顶底板变形量增大。在断层影响区域采用锚网索、单体液压支柱挑棚联合支护取得了良好的效果。     

Effect of metallurgical evolution during post-weld aging treatment on localised corrosion of resistance spot welding joints of A286 superalloy

The combined effect of resistance spot welding and precipitation hardening on the localised corrosion of A286 superalloy is studied. The specimens tested by double loop electrochemical potentiokinetic reactivation were welded in the solution treated condition, and then subjected to different precipitation hardening treatments. For both base metal and weld nugget, the maximum localised corrosion is reached when η phase is clearly observable. The fact that the localised corrosion resistance of weld nugget is different from that shown by base metal may be explained by the segregation of Ni and Ti towards the interdendritic region of weld nugget (studied by using scanning electron microscope/energy dispersive X-ray analysis).     

Validation of Models Predicting Nucleation Rates from Induction Times and Metastable Zone Widths

Three approaches for estimation of nucleation rates from induction time and metastable zone width (MSZW) were validated based on directly measured nucleation rates for paracetamol in ethanol. To quantitatively predict nucleation kinetics using Kubota's methods it is necessary to know the minimum detectable number concentration of nuclei. This was found by determination of light transmission of a series of diluted suspensions of newly nucleated crystals where the size had already been assessed by optical reflection measurement (ORM). The measured nucleation rates strongly depended on both temperature and supersaturation. The Nyvlt method predicted nucleation rates in this system reasonably well; however, it gave slightly low estimates for all temperatures. The methods of Kubota provided nucleation rates that were low by an order of magnitude.     

Post‐polymerization modification of bio‐based polymers: maximizing the high functionality of polymers derived from biomass

The renaissance of the bio‐based chemical industry over the last 20 years has seen an ever growing interest in the synthesis of new bio‐based polymers. The building blocks of these new polymers, so called platform molecules, contain significantly more chemical functionality than their petrochemical counterparts (such as ethene, propene and para‐xylene). As a result bio‐based polymers often contain greater residual chemical functionality in their chains, with groups such as alkenes and hydroxyls commonly observed. These functional groups can act as sites for post‐polymerization modification (PPM), thus further extending the range of applications for bio‐based polymers by tailoring the polymers' final properties. This mini‐review highlights some of the most recent and compelling examples of how to make use of bio‐based polymers with residual functional groups for PPM. It also looks at how the emerging interdisciplinary field of enzymatic polymer synthesis allows for increased functionality in polymers by avoiding side‐reactions as a result of milder reaction conditions, and additionally offers an alternative means of polymer surface modification. © 2018 Society of Chemical Industry     

New approaches to determine the interface height of fire smoke based on a three-layer zone model and its verification in large confined space

Large confined space has high incidence of fires, which seriously threatens the safety of people working there. Understanding the distribution of smoke in such large space is critical to fire development prediction and smoke control. Three improved methods for the stratification interface prediction of fire smoke are developed, including of improved intra-variance, integral ratio and N-percentage methods. In these methods, the interface height is determined by the vertical temperature distribution based on a three-layer smoke zone model, which is an improvement of a two-layer zone model. Thereafter, the three improved methods are applied to several typical fire cases simulated CFD to predict the smoke interface, and their applicability and reliability are verified by comparison of the smoke stratification results with the filed simulation results. Results show that the three improved methods can effectively determine the location of the three-layer zone model's interface, and they have the ability to predict smoke interface for fires with different fire source types and ventilation conditions.     

Doping-free hybrid white organic light-emitting diodes with fluorescent blue,phosphorescent green and red emission layers

Industrialized white organic light-emitting diodes (OLEDs) currently require host-guest doping, a complicated process necessitating precise control of the guest concentration to get high efficiency and stability. Two doping-free, hybrid white OLEDs with fluorescent blue, and phosphorescent green and red emissive layers (EMLs) are reported in this work. An ultra-thin red phosphorescent EML was situated in a blue-emitting electron transport layer (ETL), while the ultra-thin green phosphorescent EML was placed either in the ETL (Device 1), or the hole transport layer (HTL) (Device 2). Device 2 exhibits higher efficiency and more stable spectrum due to the enhanced utilization of excitons by ultra-thin green EML at the exciton generation zone within the HTL. Values of current efficiency (CE), power efficiency (PE), and CRI obtained for the optimized hybrid white OLEDs fabricated through a doping-free process were of 23.2 cd/A, 20.5 lm/W and 82 at 1000 cd/m², respectively.     

Numerical analysis of the peel test for characterisation of interfacial debonding in laminated glass

Laminated safety glass is widely used in construction and as automotive windshield. When the glass plies break under dynamic loading, the adhesion between the glass plies and the interlayer is key to achieving the required safety performance. However, direct measurement of the interfacial adhesive properties is not possible with the existing test methods. In corresponding calculations, material behaviour is often simplified, which leads to inaccurate results. In this article, a finite element model for the 90° peel testing of laminated glass is studied. Hydrogen bonding at the interface between poly-vinyl butyral (PVB) interlayer and glass is represented in the model by a cohesive zone. It is seen that the experimentally measured peel force can successfully be matched by the simulations, but several combinations of variables can give the same result. Therefore, a parameter study is performed to establish the influence of each variable. It is found that the peel arm, consisting of the PVB and an aluminium backing foil, cannot be regarded as a thin film. Furthermore, the exact shape of the traction-separation law governing the cohesive zone has negligible influence on the simulation results, whereas the combination of interfacial strength and fracture energy fully characterises the delamination. The simulation results show that small-strain material behaviour can no longer be assumed for the PVB material in the vicinity of the crack tip.     

Regulation of sensory nerve conduction velocity of human bodies responding to annual temperature variations in natural environments

The extensive research interests in environmental temperature can be linked to human productivity / performance as well as comfort and health; while the mechanisms of physiological indices responding to temperature variations remain incompletely understood. This study adopted a physiological sensory nerve conduction velocity (SCV) as a temperature‐sensitive biomarker to explore the thermoregulatory mechanisms of human responding to annual temperatures. The measurements of subjects’ SCV (over 600 samples) were conducted in a naturally ventilated environment over all four seasons. The results showed a positive correlation between SCV and annual temperatures and a Boltzmann model was adopted to depict the S‐shaped trend of SCV with operative temperatures from 5°C to 40°C. The SCV increased linearly with operative temperatures from 14.28°C to 20.5°C and responded sensitively for 10.19°C‐24.59°C, while tended to be stable beyond that. The subjects’ thermal sensations were linearly related to SCV, elaborating the relation between human physiological regulations and subjective thermal perception variations. The findings reveal the body SCV regulatory characteristics in different operative temperature intervals, thereby giving a deeper insight into human autonomic thermoregulation and benefiting for built environment designs, meantime minimizing the temperature‐invoked risks to human health and well‐being.     

Evaluation of air blast parameters in block cave mining using particle flow code

Air blast, a sudden mass movement of air, can occur in underground mining system where caving develops an extensive mass of unsupported rock spanning a large void. Air blast can result in injury to mine personnel, damage to equipment or disrupts mine operation. Evaluation of air blast parameters is, therefore, an essential part to develop strategies to mitigate the hazard. The properties of a muckpile or a caved zone are significant factors affecting the magnitude of air blast in particular on the undercut and extraction levels. This research investigates the effect of muckpile properties on air flow using the numerical code, PFC2D. The critical parameters such as thickness, block size and porosity (swell factor) of the muckpile have been studied to quantify how much they could change the magnitude of air pressures and velocities while the air flows through the muckpile. It was found that the porosity of the muckpile is the most effective parameter on the magnitude of air blast and by designing a thick layer of blasted rock with low porosity in the caved zone, the intensity of the air blast can be significantly reduced. The findings of this study can be used to design air blast plugs or bulkheads in order to isolate any potential air blast from the active workings, or to quantify the minimum thickness of the muckpile above extraction levels to manage air blast hazards.